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• W2066023766 abstract "More than fifty ferroelectrics belong to the Bi4Ti3O12 family, and all consist of Bi2O2 layers interleaved with perovskite-like Mn−1RnO3n+1 layers. Crystal structures of three members of the family have been refined from x-ray and neutron diffraction data, elucidating the distortions responsible for ferroelectricity. Bi2WO6 (n = 1) is orthorhombic, space group B2cb; Bi3TiNbO9 (n = 2) orthorhombic, A21am; Bi4Ti3O12 (n = 3) monoclinic, Pc, but very nearly orthorhombic, B2cb. Similar distortions occur in all three structures, with large rotational motions accompanying the polarization along a. Below the transition, a strong Bi-O bond is formed to the apex oxygen of the perovskite layer, tilting the octahedra and producing antiparallel shifts along b. Symmetry differences in the even- and odd-layered compounds can be explained by the type of strains produced in the perovskite layer. The octahedral cations (W, Ti, Nb) are the major contributors to the spontaneous polarization, moving about 0.4Å toward an octahedral edge." @default.
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• W2066023766 date "1971-10-01" @default.
• W2066023766 modified "2023-10-17" @default.
• W2066023766 title "Structural basis of ferroelectricity in the bismuth titanate family" @default.
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• W2066023766 doi "https://doi.org/10.1016/0025-5408(71)90082-1" @default.
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