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- W2066083497 abstract "Vanadium(V) oxide is reduced to bromovanadium(III) species in aqueous hydrogen bromide. Green crystals [of general formulae M2VBr5(H2O)5(M = Rb+, Cs+, pyH+)] have been isolated from such solutions; these complexes can be successively dehydrated via M2VBr5(H2O)3 and M2VBr5H2O to M2VBr5. The magnetic and spectral properties of these complexes and also of VBr3(H2O)6 are reported, in addition to X-ray powder photographs on the penta-aquocomplexes. From acetic acid solutions of hydrogen bromide, green VBr3(H2O)4 and red Et4N[VBr4(MeCO2H)2] have been isolated; the latter complex is readily converted into Et4N[VBr4(MeCN)2]. All the complexes are considered to have basically octahedral stereochemistry; the ligand field around vanadium in M2VBr5(H2O)5, M2VBr5(H2O)3, VBr3(H2O)6, and VBr3(H2O)4 consists of 4H2O and 2Br– as nearest neighbours M2VBr5 must contain bridging Br– ions." @default.
- W2066083497 created "2016-06-24" @default.
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- W2066083497 date "1969-01-01" @default.
- W2066083497 modified "2023-09-26" @default.
- W2066083497 title "Bromoaquo-complexes of vanadium(III)" @default.
- W2066083497 doi "https://doi.org/10.1039/j19690001232" @default.
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