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- W2066092004 abstract "A combination of matrix isolation technique and Fourier transform infrared spectroscopy has been used to study the low-temperature photochemistry of isothiocyanic acid HNCS. Near UV photolysis with a medium-pressure mercury lamp of the matrix isolated HNCS/DNCS precursor in nitrogen and argon led to the formation of two unobserved, so far, isomers: thiocyanic acid HSCN and isothiofulminic acid HSNC and their deuterated analogs. Both species are formed as primary products presumably via two reaction channels: formation of the [H⋯NCS] and hydrogen migration leading to the HSCN molecule and formation of the [HNC⋯S] followed by rearrangement to HSCN and HSNC species." @default.
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- W2066092004 date "2001-11-01" @default.
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- W2066092004 title "Photolysis of isothiocyanic acid HNCS in low-temperature matrices. Infrared detection of HSCN and HSNC isomers" @default.
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- W2066092004 doi "https://doi.org/10.1016/s0009-2614(01)01180-0" @default.
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