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- W2066098367 abstract "ortho-Quinodimethanes (o-QDMs) are conveniently generated cathodically in aqueous electrolyte in the presence of N-methylmaleimide, which acts as both redox mediator and dienophile. endo-Diels–Alder adducts are formed efficiently and rapidly and competition from electrohydrodimerisation of N-methylmaleimide is completely suppressed. Kinetic and coulometric evidence suggests that initial electron transfer is to a complex between the o-QDM precursor and N-methylmaleimide (hydrophobic packing)." @default.
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- W2066098367 date "2000-09-01" @default.
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- W2066098367 title "Electro-organic reactions. Part 52: Diels–Alder reactions in aqueous solution via electrogenerated quinodimethanes" @default.
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- W2066098367 doi "https://doi.org/10.1016/s0040-4039(00)01248-x" @default.
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