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- W2066101574 abstract "Abstract The reaction of [Ag(PR2)2]+ (RPh, Bun) and [M(mnt)2]2− (MNi, Pd, Pt; mnt2− = maleonitriledithiolate) gave mixed-metal complexes with the general formula of [M(mnt)2{Ag(PR3)2}]. X-ray structures of [Pt(mnt)2{Ag(PPh3)2}2] (1), [Pd(mnt)2{Ag(PPh3)2}2] (2) and [Pd(mnt)2{Ag(PBun3)2}2] (5) are similar to one another. The Ag atoms have distorted tetrahedral AgP2S2 arrangement. All complexes have MAg distances shorter than van der Waals contacts. Complex 1 dissociates in solution, whereas [Pt(mnt)2{Ag(PBun3)2}2] (4) does not appreciably. UV-Vis absorption spectra of the mixed-metal completes are not much different from those of the corresponding free [M(mnt)2]2− ions. The first oxidation potential of each mixed-metal compound shifted about 0.15 V positively from that of the corresponding free [M(mnt)2]2− ion. 31P NMR chemical shift and PAg coupling of these mixed-metal complexes do not depend significantly on the Group 10 metal atom." @default.
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- W2066101574 date "1995-03-01" @default.
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- W2066101574 title "Mixed metal complexes of groups 10 and 11 elements. The structure and properties of [M(mnt)2{Ag(PR3)2}2] (MNi, Pd, Pt; mnt2− = maleonitriledithiolate)" @default.
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- W2066101574 doi "https://doi.org/10.1016/0020-1693(94)04335-s" @default.
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