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- W2066110124 abstract "Electrochemical reduction of the complex formed by insertion of an electrogenerated nickel(0) atom into the carbon—halogen bond of a p-halogeno-substituted aromatic compound in the presence of CO2 leads to formation of the corresponding aromatic carboxylate. At room temperature the electrochemical synthesis needs catalytic quantities of nickel chloride coordinated to triphenylphosphine or 1,2-bis(diphenylphosphino)ethane. La réduction électrochimique du complexe résultant de l'insertion du nickel zérovalent électrogénéré dans la liaison carbone halogène d'un composé aromatique halogéné para-substitué en présence de CO2 conduit à la formation du carboxylate aromatique correspondant. L'électrosynthèse, menée a température ordinaire, nécessite des quantités catalytiques de chlorure de nickel ligandé soit par la triphénylphosphine en excès, soit par le 1,2-bis(diphénylphosphino)éthane." @default.
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- W2066110124 date "1984-03-01" @default.
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- W2066110124 title "Electrosynthese catalytique d'acides benzoiques para-substitues a partir du derive halogene correspondant et de l'anhydride carbonique" @default.
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- W2066110124 doi "https://doi.org/10.1016/0022-328x(84)85153-0" @default.
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