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- W2066171914 abstract "In this paper we describe a simple and efficient approach to N-glycopeptide analogues that incorporate a ketomethylene unit in place of a native amide link. Key CC bond forming steps involve the stereocontrolled addition of a functionalised allylsilane to activated sugar derivatives and the asymmetric phase-transfer alkylation of a glycine imine. Utility of this chemistry is demonstrated by the synthesis of a C-analogue of the glycopeptide core found in nephritogenoside. Regioselective ozonolysis of a 1,5-diene is also described." @default.
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- W2066171914 date "2003-12-01" @default.
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- W2066171914 title "Stereoselective approach to C-glycosylasparagines" @default.
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- W2066171914 doi "https://doi.org/10.1016/j.tetlet.2003.09.212" @default.
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