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- W2066179969 abstract "Abstract An overview is presented on the performance of Pd-complexes with phenanthroline-type ligands that are highly active catalysts for alcohol oxidation in water as well as in water/polar co-solvent mixtures. The mechanistic details of this intriguingly active and stable Pd-species are summarized. The (neocuproine)Pd(OAc) 2 catalyst is unique in that it tolerates water, polar co-solvents and a wide variety of functional groups in the alcohol. Turnover frequencies of >1500 h −1 were achieved in the latter case and a series of alcohols was oxidized with 0.1–0.5 mol% of catalyst." @default.
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- W2066179969 date "2007-07-03" @default.
- W2066179969 modified "2023-09-25" @default.
- W2066179969 title "Palladium Neocuproine Catalyzed Aerobic Oxidation of Alcohols in Aqueous Solvents" @default.
- W2066179969 cites W2950036878 @default.
- W2066179969 doi "https://doi.org/10.1002/chin.200727210" @default.
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