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- W2066201630 endingPage "9010" @default.
- W2066201630 startingPage "9005" @default.
- W2066201630 abstract "Abstract Enantiomerically pure chiral amines are of increasing importance and commercial value in the fine chemical, pharmaceutical, and agrochemical industries. Here, we describe the straightforward synthesis of chiral amines by combining the atom‐economic and environmentally friendly hydroamination of alkynes with an enantioselective hydrogenation of in situ generated imines by using inexpensive hydrogen. By following this novel approach, a wide range of terminal alkynes can be reductively hydroaminated with primary amines including alkyl‐, and arylalkynes as well as aryl and heteroaryl amines. Excellent yields and selectivities up to 94 % ee and 96 % isolated yield were obtained." @default.
- W2066201630 created "2016-06-24" @default.
- W2066201630 creator A5005182277 @default.
- W2066201630 creator A5011529576 @default.
- W2066201630 creator A5041943435 @default.
- W2066201630 creator A5048424657 @default.
- W2066201630 creator A5089629236 @default.
- W2066201630 date "2012-06-15" @default.
- W2066201630 modified "2023-10-18" @default.
- W2066201630 title "Consecutive Intermolecular Reductive Hydroamination: Cooperative Transition-Metal and Chiral Brønsted Acid Catalysis" @default.
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- W2066201630 doi "https://doi.org/10.1002/chem.201200109" @default.
- W2066201630 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22707210" @default.
- W2066201630 hasPublicationYear "2012" @default.