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- W2066240872 abstract "After modification of silica with benzoyl chloride (BC) to obtain BC-modified SiO 2 (BC-SiO 2 ), BC-SiO 2 /TiCl 4 and BC-SiO 2 /butylethylmagnesium (BEM)/TiCl 4 catalysts were prepared by treating the BC-SiO 2 with TiCl 4 directly or with BEM followed by TiCl 4 , respectively. During the modification, BC reacts with hydroxyl groups of silica. In this way the corresponding ester is anchored on the silica surface and the C=O group is coordinated with Ti and/or Mg. In addition, BEM is converted to MgCl 2 in the reaction with TiCl 4 . These catalysts have reasonable activities for ethylene or propene polymerization" @default.
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- W2066240872 date "1995-03-01" @default.
- W2066240872 modified "2023-09-26" @default.
- W2066240872 title "Olefin polymerization with titanium tetrachloride catalysts supported on surface-modified silica" @default.
- W2066240872 doi "https://doi.org/10.1002/marc.1995.030160312" @default.
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