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- W2066278344 abstract "The 1H-phosphirene 1, which bears three trimethylsilyl groups at the P-silicon atom, undergoes isomerization under photolysis conditions by a previously unknown ring expansion with concomitant shift of a trimethylsilyl group to give the 1,2-dihydro-1,2-phosphasilete 2. After a silyl/acyl exchange at phosphorus, a further ring expansion by [1,3]-Si(Tms)2 shift furnishes the 6H-1,3,6-oxaphosphasilines (2→3)." @default.
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- W2066278344 date "1999-05-03" @default.
- W2066278344 modified "2023-09-27" @default.
- W2066278344 title "The 1-Silyl-1H-phosphirene/1,2-Dihydrophosphasilete Rearrangement and Its Preparative Significance" @default.
- W2066278344 doi "https://doi.org/10.1002/(sici)1521-3765(19990503)5:5<1581::aid-chem1581>3.0.co;2-2" @default.
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