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- W2066337268 abstract "The reaction OH + HO2 → H2O + O2 (1) was studied at room temperature in several isothermal discharge-flow reactors. OH- and HO2-radicals and O-atoms were monitored with an optically pumped lmr-spectrometer. The radicals were produced by the reaction F + H2O → OH + HF and OH + HO2 H2O, F + H2O2 → HO2 + HF or H + O2 + M → HO2 + M, respectively. The influence of side reactions due to the presence of H2O2 or the possible presence of O- or H-atoms with small concentrations was investigated and eliminated or taken into account by using suitable reaction conditions. The rate constant at room temperature was found to be k1 (296 K) = (4.0 ± 1.4) · 1013 cm3/mol s. In the range 2 mbar ≤ p ≤ 14 mbar k1 is invariant with pressure." @default.
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- W2066337268 date "1982-02-01" @default.
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- W2066337268 title "Untersuchungen zur Reaktion OH + HO2 → H2O + O2 mit Hilfe eines Laser-Magnetischen Resonanz-Spektrometers" @default.
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- W2066337268 doi "https://doi.org/10.1002/bbpc.19820860206" @default.
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