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- W2066347788 abstract "The utility of the chiral [Ti(μ-O)(salen)]2 complexes (R)- and (S)-1 (H2salen was prepared from (R,R)- or (S,S)-cyclohexane-1,2-diamine and 3,5-di(tert-butyl)-2-hydroxybenzaldehyde) as catalysts for the asymmetric addition of KCN and Ac2O to aldehydes to produce O-acetylcyanohydrins was investigated. It was shown that the complexes were active at a substrate/catalyst ratio of 100 : 1 and produced the O-protected cyanohydrins with ee in the range of 60–92% at −40°. Other complexes, [Ti2(AcO)2(μ-O)(salen)2] ((R)-4) and [Ti(CF3COO)2(salen)] ((R)-5), were prepared from (R)-1 by treatment with different amounts of Ac2O and (CF3CO)2O, and their catalytic activities were tested under the same conditions. The efficiency of (R)-4 was found to be even greater than that of (R)-1, whereas (R)-5 was inactive. The synthesis of the corresponding salen complexes of VIV and VV, [V(O)(salen)] ((R)-2) and [V(O)(salen)(H2O)] [S(O)3OEt] ((R)-3), was elaborated, and their X-ray crystal structures were determined. The efficiency of (R)-3 was sufficient to produce O-acetyl derivatives of aromatic cyanohydrins with ee in the range of 80–91% at −40°." @default.
- W2066347788 created "2016-06-24" @default.
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- W2066347788 date "2002-10-01" @default.
- W2066347788 modified "2023-10-16" @default.
- W2066347788 title "Catalytic Asymmetric Synthesis of O-Acetylcyanohydrins from Potassium Cyanide, Acetic Anhydride, and Aldehydes, Promoted by Chiral Salen Complexes of Titanium(IV) and Vanadium(V)" @default.
- W2066347788 doi "https://doi.org/10.1002/1522-2675(200210)85:10<3301::aid-hlca3301>3.0.co;2-2" @default.
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