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- W2066403606 abstract "The interaction of cyclomaltohexaose (a-cyclodextrin, aCD) with alkyl glycosides (AG) in solution in D2O was investigated by n.m.r. spectroscopy. aCD induced significant shifts of 1H and 13C signals (especially for the alkyl chain and the anomeric center) of octyl and dodecyl a- and β-d-glucopyranoside, dodecyl β-maltoside, and octadecyl β-d-glucopyranoside. The 1H signals of the C12 and C18 AG, which were tightly bound in the original micelles, also sharpened dramatically. The CD-induced 13C shifts and changes in spin-lattice relaxation times for the octyl β-glucoside were largest for C-4/C-7 of the alkyl chain as expected for inclusion of the chain in the CD cavity. The CD disrupted the AG aggregates, with inclusion of the hydrophobic chains in their macrocycles, suggesting their use for controlling the solution properties of alkyl glycosides and glycolipids." @default.
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- W2066403606 date "1990-04-01" @default.
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- W2066403606 title "Interaction of cyclodextrins (cyclomalto-oligosaccharides) with glycolipids: n.m.r. studies of aqueous systems of cyclo-maltohexaose and alkyl glycosides" @default.
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- W2066403606 doi "https://doi.org/10.1016/0008-6215(90)84185-w" @default.
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