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- W2066422379 abstract "Keggin-type phosphomolybdic acid (H3PMo12O40) promoted the formation of a cation radical of tetra(thienylthio)-tetrathiafulvalene (TT-TTF), consequently resulting in a cation radical complex [(TT-TTF)+•]3[(PMo12O40)3−](CH2Cl2), which shows self-assembly in solution and forms microtubes. The molecular level structure of the microtube is evaluated by X-ray diffraction analysis, which reveals that the microtube is produced via various non-covalent interactions in the hierarchical assembly process: the electrostatic interactions between (TT-TTF)+• and (PMo12O40)3− afford an organic–inorganic hybrid triangular nanocluster [(TT-TTF)+•]3[(PMo12O40)3−] as the building block; the strong π–π interactions between (TT-TTF)+• result in the cluster-based two-dimensional honeycomb nanosheet; the van der Waals forces between the nanosheets lead to the propagation along the third direction to form a three-dimensional supramolecular framework possessing nano-sized channels." @default.
- W2066422379 created "2016-06-24" @default.
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- W2066422379 date "2015-01-01" @default.
- W2066422379 modified "2023-09-24" @default.
- W2066422379 title "Honeycomb supramolecular frameworks of organic–inorganic hybrid cluster composed of cation radical and Keggin-type polyoxometalate" @default.
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- W2066422379 doi "https://doi.org/10.1039/c5ce00510h" @default.
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