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- W2066422416 abstract "The initial stage in the radiation polymerization of the hydroxyethyl methacrylate water system at low temperatures was studied. The polymerization was accelerated by the presence of water; the effect increased with rising temperature above Tg. The polymerization rate had a maximum near −50°. The initiating and propagating radicals were identified by studies with ESR. Irradiated hydroxyethyl methacrylate at low temperatures gave a 7-line spectrum, which was assigned to the initiating radical having equivalent protons. This spectrum was changed to a 9-line spectrum at −120 to −100°; it was assigned to the propagating radical. The temperature dependence of the ESR spectrum of irradiated hydroxyethyl methacrylate-water systems was studied to examine the effect of water on the propagating radical." @default.
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- W2066422416 date "1983-01-01" @default.
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- W2066422416 title "Initial stage in radiation polymerization of hydroxyethyl methacrylate-water system at low temperatures" @default.
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- W2066422416 doi "https://doi.org/10.1016/0014-3057(83)90189-1" @default.
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