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- W2066462783 abstract "There is overwhelming evidence that meteorites bring α-methylated amino acids to earth with some l(S) enantiomeric excess. How does that get transferred into normal biological molecules? In this brief account, we show that an α-methylated amino acid, d(R)-α-methylvaline, can react with pyruvate and phenylpyruvate salts in dry mixtures to form alanine and phenylalanine with l enantiomeric excesses, under sensible prebiotic conditions. Thus the meteoritic l(S) excesses of this compound would produce excess d-alanine and d-phenylalanine, which are found in some organisms." @default.
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- W2066462783 date "2006-03-01" @default.
- W2066462783 modified "2023-10-10" @default.
- W2066462783 title "Partial transfer of enantioselective chiralities from α-methylated amino acids, known to be of meteoritic origin, into normal amino acids" @default.
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- W2066462783 doi "https://doi.org/10.1016/j.tetlet.2006.01.018" @default.
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