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- W2066467052 abstract "To study boron isotopic fractionation at high pressure, column chromatography operated in the breakthrough manner was performed at 2.0 MPa at 25.0 °C. The fractionation factor (S) between boron adsorbed onto strongly basic anion-exchange resin and boron in solution was obtained as 1.013, which was smaller than the values at 0.1 MPa (atmospheric pressure) found in literature. The pressure dependence of S was discussed based on the polymerization of boron in the solution and resin phases and on the occurrence of the pressure dependent isotope effect relating to the molar volume changes of boron species upon isotope substitution." @default.
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- W2066467052 date "2006-10-01" @default.
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- W2066467052 title "An anion-exchange chromatographic study on boron isotopic fractionation at 2MPa at 293K" @default.
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- W2066467052 doi "https://doi.org/10.1016/j.chroma.2006.07.031" @default.
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