Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066507961> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2066507961 endingPage "366" @default.
- W2066507961 startingPage "355" @default.
- W2066507961 abstract "The trigonal β-LiNaSO4 low temperature polymorph belongs to the family of double sulphates with general formula LiMSO4 (M=Na, NH4, Rb, …), which have very specific electrical properties. In this paper we present the β-LiNaSO4 theoretical growth morphology based on the Hartman–Perdok theory. Therefore, Periodic Bond Chains (PBCs) have been identified in order to determine the influence of the crystal structure on the crystal morphology. The shortest PBC is parallel to 〈1 0 0〉 and consists of a one-step proto-PBC with sulphate(I)–cation–sulphate(I, 1 0 0) strong bonds. All the other PBCs are built up from strong bonds in two or more consecutive steps, e.g., sulphate (I)–cation–sulphate(II)–cation–sulphate (I, u v w). The corresponding F forms are in order of decreasing dhkl: {101̄0}, {101̄1}, {0 0 0 2}, {101̄2}, {112̄0}={21̄1̄0}, {112̄2}={21̄1̄2}, … For many F forms several different slice configurations can be defined. Attachment energies have been calculated in electrostatic point charge models with formal charges. In addition, the effect of covalent S–O bonds on the growth forms has been taken into account by decreasing the effective charge on oxygen, qO. The theoretical growth form of β-LiNaSO4 based on attachment energies calculated in the LiNaS6+O42− point charge model shows the hexagonal prism {101̄0}, the hexagonal pyramid {101̄1} and the pedion (0 0 0 1). When the influence of the S–O bond decreases (LiNaS4+O41.5− model), the habit is slightly less elongated parallel to the c-axis due to the increased relative morphological importance of the pyramid form with respect to the prism. When we assume that the hexagonal prism face grows with halved slices d202̄0 and thus using the attachment energies of Ea202̄0 instead of those of Ea101̄0, the growth forms changes drastically by the absence of the hexagonal prism form in both models. In addition, the trigonal prism {112̄0} is present as a minor form on this LiNaS4+O41.5− model with halved d202̄0 slices. Experimentally grown LiNaSO4 crystals show habits that deviate from the theoretical growth forms. This must be due to external factors such as supersaturation and interaction of the crystal surface with the aqueous solutions during the growth. Growth experiments confirm that the growth morphology is strongly influenced by the degree of supersaturation." @default.
- W2066507961 created "2016-06-24" @default.
- W2066507961 creator A5039049122 @default.
- W2066507961 creator A5070124214 @default.
- W2066507961 date "2001-11-01" @default.
- W2066507961 modified "2023-10-14" @default.
- W2066507961 title "Hartman–Perdok analysis of crystal morphology and interface topology of β-LiNaSO4" @default.
- W2066507961 cites W1497276876 @default.
- W2066507961 cites W1525290734 @default.
- W2066507961 cites W1651304803 @default.
- W2066507961 cites W1979601153 @default.
- W2066507961 cites W2002280107 @default.
- W2066507961 cites W2003457172 @default.
- W2066507961 cites W2006114311 @default.
- W2066507961 cites W2036589044 @default.
- W2066507961 cites W2047704796 @default.
- W2066507961 cites W2085159536 @default.
- W2066507961 cites W2124468454 @default.
- W2066507961 doi "https://doi.org/10.1016/s0022-0248(01)01549-4" @default.
- W2066507961 hasPublicationYear "2001" @default.
- W2066507961 type Work @default.
- W2066507961 sameAs 2066507961 @default.
- W2066507961 citedByCount "1" @default.
- W2066507961 countsByYear W20665079612016 @default.
- W2066507961 crossrefType "journal-article" @default.
- W2066507961 hasAuthorship W2066507961A5039049122 @default.
- W2066507961 hasAuthorship W2066507961A5070124214 @default.
- W2066507961 hasConcept C10138342 @default.
- W2066507961 hasConcept C114614502 @default.
- W2066507961 hasConcept C115624301 @default.
- W2066507961 hasConcept C121332964 @default.
- W2066507961 hasConcept C128765274 @default.
- W2066507961 hasConcept C145148216 @default.
- W2066507961 hasConcept C162324750 @default.
- W2066507961 hasConcept C178790620 @default.
- W2066507961 hasConcept C180577832 @default.
- W2066507961 hasConcept C182306322 @default.
- W2066507961 hasConcept C184720557 @default.
- W2066507961 hasConcept C185592680 @default.
- W2066507961 hasConcept C188082385 @default.
- W2066507961 hasConcept C199360897 @default.
- W2066507961 hasConcept C26456737 @default.
- W2066507961 hasConcept C2777722419 @default.
- W2066507961 hasConcept C2781285689 @default.
- W2066507961 hasConcept C33923547 @default.
- W2066507961 hasConcept C41008148 @default.
- W2066507961 hasConcept C499950583 @default.
- W2066507961 hasConcept C54355233 @default.
- W2066507961 hasConcept C62520636 @default.
- W2066507961 hasConcept C8010536 @default.
- W2066507961 hasConcept C86803240 @default.
- W2066507961 hasConceptScore W2066507961C10138342 @default.
- W2066507961 hasConceptScore W2066507961C114614502 @default.
- W2066507961 hasConceptScore W2066507961C115624301 @default.
- W2066507961 hasConceptScore W2066507961C121332964 @default.
- W2066507961 hasConceptScore W2066507961C128765274 @default.
- W2066507961 hasConceptScore W2066507961C145148216 @default.
- W2066507961 hasConceptScore W2066507961C162324750 @default.
- W2066507961 hasConceptScore W2066507961C178790620 @default.
- W2066507961 hasConceptScore W2066507961C180577832 @default.
- W2066507961 hasConceptScore W2066507961C182306322 @default.
- W2066507961 hasConceptScore W2066507961C184720557 @default.
- W2066507961 hasConceptScore W2066507961C185592680 @default.
- W2066507961 hasConceptScore W2066507961C188082385 @default.
- W2066507961 hasConceptScore W2066507961C199360897 @default.
- W2066507961 hasConceptScore W2066507961C26456737 @default.
- W2066507961 hasConceptScore W2066507961C2777722419 @default.
- W2066507961 hasConceptScore W2066507961C2781285689 @default.
- W2066507961 hasConceptScore W2066507961C33923547 @default.
- W2066507961 hasConceptScore W2066507961C41008148 @default.
- W2066507961 hasConceptScore W2066507961C499950583 @default.
- W2066507961 hasConceptScore W2066507961C54355233 @default.
- W2066507961 hasConceptScore W2066507961C62520636 @default.
- W2066507961 hasConceptScore W2066507961C8010536 @default.
- W2066507961 hasConceptScore W2066507961C86803240 @default.
- W2066507961 hasIssue "1-2" @default.
- W2066507961 hasLocation W20665079611 @default.
- W2066507961 hasOpenAccess W2066507961 @default.
- W2066507961 hasPrimaryLocation W20665079611 @default.
- W2066507961 hasRelatedWork W1861237750 @default.
- W2066507961 hasRelatedWork W1980622397 @default.
- W2066507961 hasRelatedWork W1984275137 @default.
- W2066507961 hasRelatedWork W2003077989 @default.
- W2066507961 hasRelatedWork W2042204083 @default.
- W2066507961 hasRelatedWork W2061216269 @default.
- W2066507961 hasRelatedWork W2086236412 @default.
- W2066507961 hasRelatedWork W2147063087 @default.
- W2066507961 hasRelatedWork W2386326306 @default.
- W2066507961 hasRelatedWork W2741677165 @default.
- W2066507961 hasVolume "233" @default.
- W2066507961 isParatext "false" @default.
- W2066507961 isRetracted "false" @default.
- W2066507961 magId "2066507961" @default.
- W2066507961 workType "article" @default.