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- W2066561646 abstract "Magnetic susceptibility measurements are reported for the compounds CfN, CfAs and CfSb. These semimetallic compounds evhibit the NaCl-type cubic crystal structure. For these magnetic measurements the temperature was varied from 4.2 K to 340 K and the magnetic field from 1 to 50 kG. The paramagnetic effective moments derived from Curie-Weiss fits to the data agree, within evperimental error, with a theoretical value of 10.2 μB calculated for the 5f9 electronic state of Cf3+ assuming an intermediate-coupling model. Deviations of the susceptibility from Curie-Weiss behavior at lower temperatures are indicative of magnetic ordering and crystal-field splitting of the ground state. The ordering temperatures of these californium compounds are considerably lower than those observed previously for pnictides of curium and berkelium. This decrease in ordering temperature with increasing atomic number is consistent with the trend observed for the lanthanide monopnictides." @default.
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- W2066561646 date "1986-07-01" @default.
- W2066561646 modified "2023-09-23" @default.
- W2066561646 title "Magnetic susceptibility of CfN, CfAs and CfSb" @default.
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- W2066561646 doi "https://doi.org/10.1016/0022-5088(86)90548-5" @default.
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