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• W2066561915 abstract "The benefit of miniaturization towards the nanoscale of electroanalytical systems was evaluated by assessment of the sensitivity of the response. Ion transfer voltammetry across the interface between two immiscible electrolyte solutions (ITIES) was employed as the basis for detection of nonredoxactive ions. The analytical sensitivity increased on miniaturisation of the interface from millimetre-, to micrometre-, to nanometre-scale, with an improvement in sensitivity of more than three orders of magnitude. This is due to the enhanced mass transport via convergent diffusion as the size of the ITIES is minimised. These results illustrate the benefit of miniaturisation of electrochemical detection methods to the nanoscale." @default.
• W2066561915 created "2016-06-24" @default.
• W2066561915 creator A5014703396 @default.
• W2066561915 creator A5077627198 @default.
• W2066561915 date "2011-03-16" @default.
• W2066561915 modified "2023-10-18" @default.
• W2066561915 title "Enhanced Electroanalytical Sensitivity via Interface Miniaturisation: Ion Transfer Voltammetry at an Array of Nanometre Liquid-Liquid Interfaces" @default.
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• W2066561915 doi "https://doi.org/10.1002/elan.201000667" @default.
• W2066561915 hasPublicationYear "2011" @default.
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