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- W2066576032 abstract "Very small crystals of anhydrous guanine (systematic name: 2-amino-1,7-dihydro-6H-purin-6-one), C5H5N5O, were obtained from an attempted solvothermal synthesis of a potassium complex. Data were collected at 120 K using a synchrotron radiation source. There is one essentially planar molecule in the asymmetric unit. Molecules are linked to each other by N—H⋯N and N—H⋯O hydrogen bonds to form sheets, between which there are π–π stacking interactions. This crystal structure determination demonstrates conclusively that, in the absence of any solvent or other molecules, guanine exists as the amino–keto tautomer in the solid state, with H atoms attached to N1 and N7 (purine numbering), unlike its monohydrate, which has H atoms on N1 and N9." @default.
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- W2066576032 date "2006-07-29" @default.
- W2066576032 modified "2023-10-06" @default.
- W2066576032 title "Anhydrous guanine: a synchrotron study" @default.
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- W2066576032 doi "https://doi.org/10.1107/s0108270106026011" @default.
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