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- W2066577050 abstract "The electrolysis of α-chlorovaleric, α-chlorocaproic, and α-chloroisobutyric acids in methanol gave none of the Kolbe dimer; the main products were chloroester and hydrogen ester with aldehydes and acetals formed in lesser amounts. In water, straight chain α-chloroacids gave dimeric esters as the major product. However, Kolbe dimer was formed in fairly good yields together with small amounts of fluoroester and acetal, when α-fluorocaproic and α-fluoroheptanoic acids were electrolyzed in methanol. No Kolbe dimer was produced from 2-fluoro-2-ethylbutanoic and α-fluorophenylacetic acids; the corresponding ketone or aldehyde was the major product." @default.
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- W2066577050 date "1971-08-15" @default.
- W2066577050 modified "2023-09-26" @default.
- W2066577050 title "Electrolysis of α-Chloro- and α-Fluorocarboxylic Acids" @default.
- W2066577050 doi "https://doi.org/10.1139/v71-445" @default.
- W2066577050 hasPublicationYear "1971" @default.
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