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- W2066620132 abstract "Complexes of poly(ethylene oxide) (PEO), with various alkali metal salts are known to exhibit ionic conductivities which exceed 10−5(Ωcm)−1 at moderate temperatures. We have employed IR and Raman spectroseopy to study well characterized samples of the following polymer-salt complexes: PEO·NaBr, PEO·NaI, PEO·NaSCN, PEO·NaBF4, PEO·NaCF3SO3, PEO·KSCN, PEO·RbSCN and PEO·CsSCN. Cation-dependent vibrational bands observed in the far IR and M-On symmetric stretching bands observed in the Raman support a cation-oxygen atom interaction, and indicate the polyether chain may wrap around the cations. In particular, NaX and KX complexes of PEO are believed to have a helical configuration for the polymer which differs from that of pure PEO. Some general rules are presented for polymer-salt complex formation." @default.
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- W2066620132 date "1981-01-01" @default.
- W2066620132 modified "2023-10-05" @default.
- W2066620132 title "Vibrational spectroscopy and structure of polymer electrolytes, poly(ethylene oxide) complexes of alkali metal salts" @default.
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- W2066620132 doi "https://doi.org/10.1016/0022-3697(81)90030-5" @default.
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