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- W2066634987 abstract "Abstract Fundamental concepts pertaining to the stereochemistry paths of polar additionelimination (nucleophilic substitution) reactions at phosphate phosphorus centers are reviewed and employed to analyze 18O exchange reactions catalyzed by inorganic pyrophosphatase and mitochondrial ATP synthetase. The analysis suggests reasonable choices for the stereochemistry path of the 18O exchanges. This, in turn, permits reasonable choices for the stereochemistry paths of hydrolysis of pyrophosphate catalyzed by pyrophosphatase and of hydrolysis and synthesis of ATP catalyzed by ATP synthetase." @default.
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- W2066634987 date "1973-01-01" @default.
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- W2066634987 title "Stereochemical reaction mechanism formulations for enzyme-catalyzed pyrophosphate hydrolysis, ATP hydrolysis, and ATP synthesis" @default.
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- W2066634987 doi "https://doi.org/10.1016/0045-2068(73)90021-7" @default.
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