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• W2066663313 abstract "The lithium-ion exchange rate capability of various commercial graphite materials are evaluated using galvanostatic charge/discharge cycling in a half-cell configuration over a wide range of C-rates (0.1 similar to 60C). The results confirm that graphite is capable of de-intercalating stored charge at high rates, but has a poor intercalating rate capability. Decreasing the graphite coating thickness leads to a limited rate performance improvement of the electrode. Reducing the graphite particle size shows enhanced C-rate capability but with increased irreversible capacity loss (ICL). It is demonstrated that the rate of intercalation of lithium-ions into the graphite is significantly limited compared with the corresponding rate of de-intercalation at high C-rates. For the successful utilisation of commercially available conventional graphite as a negative electrode in a lithium-ion capacitor (LIC), its intercalation rate capability needs to be improved or oversized to accommodate high charge rates." @default.
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• W2066663313 date "2010-03-01" @default.
• W2066663313 modified "2023-10-17" @default.
• W2066663313 title "Rate capability of graphite materials as negative electrodes in lithium-ion capacitors" @default.
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• W2066663313 doi "https://doi.org/10.1016/j.electacta.2010.01.059" @default.
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