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• W2066682011 abstract "Abstract A monomeric aluminum hydride complex bearing substituted pyrrolyl ligands, AlH[C 4 H 3 N(CH 2 NMe 2 )‐2] 2 ( 1 ), was synthesized and structurally characterized. To further confirm the presence of AlH bonds, the compound AlD[C 4 H 3 N(CH 2 NMe 2 )‐2] 2 ([D] 1 ) was synthesized by reacting LiAlD 4 with [C 4 H 4 N(CH 2 NMe 2 )‐2]. Compound 1 and [D] 1 react with phenyl isothiocyanate yielding Al[C 4 H 3 N(CH 2 NMe 2 )‐2] 2 [η 3 ‐SCHNPh] ( 2 ) and Al[C 4 H 3 N(CH 2 NMe 2 )‐2] 2 [η 3 ‐SCDNPh] ([D] 2 ) by insertion. The reactions of 1 with 9‐fluorenone and benzophenone generated the unusual aluminum alkoxide complexes 3 and 4 , respectively, through intramolecular proton abstraction and C–C coupling. A mechanistic study shows that 9‐fluorenone coordinates to [D] 1 and releases one equivalent of HD followed by C–C coupling and hydride transfer to yield the final product. Reduction of benzil with 1 affords aluminum enediolate complex 5 in moderate yield. Mechanistic studies also showed that the benzil was inserted into the aluminum hydride bond of [D] 1 through hydroalumination followed by proton transfer to generate the final product [D] 5 . All new complexes have been characterized by 1 H and 13 C NMR spectroscopy and X‐ray crystallography." @default.
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• W2066682011 date "2006-03-27" @default.
• W2066682011 modified "2023-10-18" @default.
• W2066682011 title "Insertion, Reduction, and Carbon–Carbon Coupling Induced by Monomeric Aluminum Hydride Compounds Bearing Substituted Pyrrolyl Ligands" @default.
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• W2066682011 doi "https://doi.org/10.1002/chem.200500989" @default.
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