FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066703497> ?p ?o ?g. }

• W2066703497 endingPage "12756" @default.
• W2066703497 startingPage "12750" @default.
• W2066703497 abstract "Passivation of (100) silicon surfaces using alkyl Grignard reagents is explored via electrochemical and thermal grafting methods. The electrochemical behavior of silicon in methyl or ethyl Grignard reagents in tetrahydrofuran is investigated using cyclic voltammetry. Surface morphology and chemistry are investigated using atomic force microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). Results show that electrochemical pathways provide an efficient and more uniform passivation method relative to thermal methods, and XPS results demonstrate that electrografted terminations are effective at limiting native oxide formation for more than 55 days in ambient conditions. A two-electron per silicon mechanism is proposed for electrografting a single (1:1) alkyl group per (100) silicon atom. The mechanism includes oxidation of two Grignard species and subsequent hydrogen abstraction and alkylation reaction resulting in a covalent attachment of alkyl groups with silicon." @default.
• W2066703497 created "2016-06-24" @default.
• W2066703497 creator A5055743066 @default.
• W2066703497 creator A5070424014 @default.
• W2066703497 creator A5072340381 @default.
• W2066703497 date "2009-09-01" @default.
• W2066703497 modified "2023-09-27" @default.
• W2066703497 title "Electrochemical and Thermal Grafting of Alkyl Grignard Reagents onto (100) Silicon Surfaces" @default.
• W2066703497 cites W1972091231 @default.
• W2066703497 cites W1973902558 @default.
• W2066703497 cites W1982264852 @default.
• W2066703497 cites W1985718625 @default.
• W2066703497 cites W1987158894 @default.
• W2066703497 cites W1996210766 @default.
• W2066703497 cites W2000285697 @default.
• W2066703497 cites W2002258185 @default.
• W2066703497 cites W2010486086 @default.
• W2066703497 cites W2011488302 @default.
• W2066703497 cites W2015186152 @default.
• W2066703497 cites W2028188610 @default.
• W2066703497 cites W2033172218 @default.
• W2066703497 cites W2056659301 @default.
• W2066703497 cites W2060582030 @default.
• W2066703497 cites W2060967236 @default.
• W2066703497 cites W2062366276 @default.
• W2066703497 cites W2063140846 @default.
• W2066703497 cites W2067494672 @default.
• W2066703497 cites W2068944942 @default.
• W2066703497 cites W2070967291 @default.
• W2066703497 cites W2080128766 @default.
• W2066703497 cites W2084005992 @default.
• W2066703497 cites W2086481311 @default.
• W2066703497 cites W2087422875 @default.
• W2066703497 cites W2091061110 @default.
• W2066703497 cites W2091305386 @default.
• W2066703497 cites W2126812921 @default.
• W2066703497 cites W2136268893 @default.
• W2066703497 cites W2146211324 @default.
• W2066703497 cites W2178561717 @default.
• W2066703497 cites W2322246389 @default.
• W2066703497 cites W292460434 @default.
• W2066703497 doi "https://doi.org/10.1021/la9018103" @default.
• W2066703497 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19722602" @default.
• W2066703497 hasPublicationYear "2009" @default.
• W2066703497 type Work @default.
• W2066703497 sameAs 2066703497 @default.
• W2066703497 citedByCount "18" @default.
• W2066703497 countsByYear W20667034972012 @default.
• W2066703497 countsByYear W20667034972013 @default.
• W2066703497 countsByYear W20667034972014 @default.
• W2066703497 countsByYear W20667034972015 @default.
• W2066703497 countsByYear W20667034972016 @default.
• W2066703497 countsByYear W20667034972021 @default.
• W2066703497 countsByYear W20667034972022 @default.
• W2066703497 crossrefType "journal-article" @default.
• W2066703497 hasAuthorship W2066703497A5055743066 @default.
• W2066703497 hasAuthorship W2066703497A5070424014 @default.
• W2066703497 hasAuthorship W2066703497A5072340381 @default.
• W2066703497 hasConcept C127413603 @default.
• W2066703497 hasConcept C147789679 @default.
• W2066703497 hasConcept C160892712 @default.
• W2066703497 hasConcept C17525397 @default.
• W2066703497 hasConcept C175708663 @default.
• W2066703497 hasConcept C178790620 @default.
• W2066703497 hasConcept C179104552 @default.
• W2066703497 hasConcept C185592680 @default.
• W2066703497 hasConcept C192562407 @default.
• W2066703497 hasConcept C2776701986 @default.
• W2066703497 hasConcept C2777869211 @default.
• W2066703497 hasConcept C2779227376 @default.
• W2066703497 hasConcept C2780263894 @default.
• W2066703497 hasConcept C2780471494 @default.
• W2066703497 hasConcept C33574316 @default.
• W2066703497 hasConcept C40875361 @default.
• W2066703497 hasConcept C42360764 @default.
• W2066703497 hasConcept C52859227 @default.
• W2066703497 hasConcept C544956773 @default.
• W2066703497 hasConceptScore W2066703497C127413603 @default.
• W2066703497 hasConceptScore W2066703497C147789679 @default.
• W2066703497 hasConceptScore W2066703497C160892712 @default.
• W2066703497 hasConceptScore W2066703497C17525397 @default.
• W2066703497 hasConceptScore W2066703497C175708663 @default.
• W2066703497 hasConceptScore W2066703497C178790620 @default.
• W2066703497 hasConceptScore W2066703497C179104552 @default.
• W2066703497 hasConceptScore W2066703497C185592680 @default.
• W2066703497 hasConceptScore W2066703497C192562407 @default.
• W2066703497 hasConceptScore W2066703497C2776701986 @default.
• W2066703497 hasConceptScore W2066703497C2777869211 @default.
• W2066703497 hasConceptScore W2066703497C2779227376 @default.
• W2066703497 hasConceptScore W2066703497C2780263894 @default.
• W2066703497 hasConceptScore W2066703497C2780471494 @default.
• W2066703497 hasConceptScore W2066703497C33574316 @default.
• W2066703497 hasConceptScore W2066703497C40875361 @default.
• W2066703497 hasConceptScore W2066703497C42360764 @default.
• W2066703497 hasConceptScore W2066703497C52859227 @default.
• W2066703497 hasConceptScore W2066703497C544956773 @default.
• W2066703497 hasIssue "21" @default.
• W2066703497 hasLocation W20667034971 @default.

• next