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- W2066706913 abstract "The lifetime broadening of some rare-earth ${L}_{mathrm{III}}$-edge x-ray absorption spectra (XAS) is partially removed by deconvolving high quality data. The ligand field splitting of dipolar resonances is clearly resolved. Exposed pre-edge structure is compared to atomic multiplet calculations of the $2pensuremath{rightarrow}4f$ quadrupolar excitations. Ratios are thereby determined for the quadrupolar/dipolar oscillator strengths. Deconvolved XAS data of Ho${(mathrm{N}{mathrm{O}}_{3})}_{3}$ are compared to inelastic x-ray scattering measurements showing experimentally that the latter cannot reproduce a narrowed XAS." @default.
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- W2066706913 title "Deconvolution of lifetime broadening at rare-earth<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi>L</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant=normal>III</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>edges compared to resonant inelastic x-ray scattering measurements" @default.
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- W2066706913 doi "https://doi.org/10.1103/physrevb.54.14877" @default.
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