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- W2066722015 abstract "In this report, we present a new lithographic approach to prepare patterned surfaces. Self-assembled monolayers (SAMs) of the acid-labile trimethylsilyl ether (TMS-OC(11)H(22)S)(2) (TMS adsorbate) was formed on gold. 5-Mercapto-2-benzimidazole sulfonic acid sodium salt (MBS-Na(+)) was used as a ligand for gold nanoparticles. These monolayer-protected gold colloids (MPCs) were transformed into the catalytically active H(+)-form by ion exchange. This colloid-bound catalyst hydrolyzed the TMS adsorbate (TMS-OC(11)H(22)S)(2) both in solution and when self-assembled on gold surfaces. Microcontact printing of the active colloid-bound catalyst on the preformed TMS SAM led to the deposition of the colloid onto the SAMs. After the catalyst nanoparticles were rinsed off, a patterned surface was created as shown by AFM." @default.
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- W2066722015 date "2003-03-13" @default.
- W2066722015 modified "2023-10-06" @default.
- W2066722015 title "Sulfonic Acid-Functionalized Gold Nanoparticles: A Colloid-Bound Catalyst for Soft Lithographic Application on Self-Assembled Monolayers" @default.
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- W2066722015 doi "https://doi.org/10.1021/ja0271431" @default.
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