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- W2066745308 abstract "Abstract A bimetallic cluster complex, [{Zn(2,2′-bipy)3}2V4O12] · 11H2O(2,2′-bipy=2,2′-bipyridine), has been synthesized hydrothermally by a new and more efficient modified way. This complex crystallizes in the monoclinic system with space group C2/c and cell parameters a=21.9417(5) Å, b=14.0337(3) Å, c=23.8513(7) Å. β=106.2(8)° and Z=4 with R1=0.0342. The structure of the complex consists of a discrete anion cluster [V4O12]4− and the cation {Zn(2,2′-bipy)3}2+, which is connected by electrostatic force. IR spectra and quantum chemistry data for this complex are given and discussed. Keywords: synthesiscrystal structureoxovanadium complexquantum chemistry Acknowledgments We wish to express our sincere thanks to SPR for ROCS, SEM, and National Natural Science Foundation of China (No. 20571036) for financial assistance." @default.
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- W2066745308 date "2005-12-01" @default.
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- W2066745308 title "Synthesis, Structure Characterization, and Quantum Chemistry of a Discrete Cluster [{Zn(2,2′-bipy)3}2V4O12]·11H2O (2,2′-bipy=2,2′-bipyridine)" @default.
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- W2066745308 doi "https://doi.org/10.1080/15533170500360339" @default.
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