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- W2066753744 abstract "First-principles calculations show that Bi on Cd site in CdTe can be either a donor ${text{Bi}}_{text{Cd}}^{+}$ or an acceptor ${text{Bi}}_{text{Cd}}^{ensuremath{-}}$, depending on the Fermi level. The ${text{Bi}}_{text{Cd}}^{ensuremath{-}}$ can bind a substitutional O $({text{O}}_{text{Te}})$ with large binding energy of 1.40 eV. The calculated $(0/ensuremath{-})$ transition level for ${text{Bi}}_{text{Cd}}^{ensuremath{-}}{text{-O}}_{text{Te}}$ complex is in good agreement with experimentally observed deep hole trapping level. Bi can also substitute Te to form an acceptor. The amphoteric nature of Bi in CdTe results in the pinning of the Fermi level and the high resistivity. The transition of the CdTe samples from semi-insulating to $p$ type at high Bi doping levels is explained by the formation of secondary phase that contains Bi and Te." @default.
- W2066753744 created "2016-06-24" @default.
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- W2066753744 date "2008-11-12" @default.
- W2066753744 modified "2023-10-18" @default.
- W2066753744 title "Bismuth-induced deep levels and carrier compensation in CdTe" @default.
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- W2066753744 doi "https://doi.org/10.1103/physrevb.78.172105" @default.
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