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- W2066772421 abstract "First generation Grubbs catalyst [RuCl2(PCy3)2(CHPh)] and related complexes of a general formula [RuCl2(PCy3)2(CHR)], where R is an aromatic or methyl group, undergo efficient reaction with trimethylsilylacetylene and related silylacetylenes to form vinyl carbene complexes [RuCl2(PCy3)2(CHCHCHR)] and disiloxane. The reaction requires the presence of water in the reaction medium. It is a convenient method for the high-yield synthesis of ruthenium vinyl carbene complexes. For benzylidene complexes, the reaction gives exclusively E-geometry of vinyl carbene ligand." @default.
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- W2066772421 date "2014-02-01" @default.
- W2066772421 modified "2023-10-14" @default.
- W2066772421 title "Efficient synthesis of ruthenium vinyl carbene complexes" @default.
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- W2066772421 doi "https://doi.org/10.1016/j.jorganchem.2013.12.002" @default.
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