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• W2066791490 abstract "X-ray standing-wave measurements on Cs and Rb adlayers on the Si(111)7ifmmodetimeselsetexttimesfi{}7 surface are presented. Low [ensuremath{approxeq}0.06 monolayer (ML)] and medium (ensuremath{approxeq}0.15 ML) coverages have been analyzed. The (111) and the (1ifmmodebarelsetextasciimacronfi{}11) reflections have been used. Since the experimental results clearly indicate that multisite occupancy takes place, the threefold hollow (${mathit{H}}_{3}$), the threefold filled (${mathit{T}}_{4}$), and all the dangling-bond sites have been considered as possible adsorption sites. Distinction has been made between the faulted and the unfaulted half of the 7ifmmodetimeselsetexttimesfi{}7 cell. The Si--alkali-metal bond length has been assumed to be the sum of the covalent radii of the two elements. Our results indicate that both Rb and Cs adsorb preferentially on the ${mathit{H}}_{3}$ and the ${mathit{T}}_{4}$ sites. The remaining atoms adsorb most at the atop sites for Rb and at the adatom sites (i.e., on top of the silicon adatom) for Cs." @default.
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• W2066791490 date "1992-11-15" @default.
• W2066791490 modified "2023-09-24" @default.
• W2066791490 title "Structural study of the Si–alkali-metal interface with x-ray standing waves" @default.
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• W2066791490 doi "https://doi.org/10.1103/physrevb.46.13631" @default.
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