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- W2066827178 abstract "The well-known van der Waals system formed by the highly polar HF molecule and the helium atom is studied theoretically from the point of view of the rotationally predissociative behaviour ofits bound states. A potential energy surface for its rigid-rotor representation is employed to generate the necessary bound and continuum states via three different procedures. The generally weak atom—diatom couplings and the widely spaced rotational levels of the isolated diatom are found to be mostly responsible for the existence of well-spaced, nearly isolated narrow resonance." @default.
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- W2066827178 date "1984-11-01" @default.
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- W2066827178 title "Rotational predissociation in polar systems. The He - HF example" @default.
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- W2066827178 doi "https://doi.org/10.1016/0009-2614(84)85528-1" @default.
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