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- W2066920538 abstract "The TbCu7-type structure in bulk Pr–Hf–Co alloys was obtained by high-temperature homogenization of alloys adjacent to the PrCo5 composition. At 1150 °C, the homogeneity range of binary PrCo5+δ structure stretches to 84.5 at.% Co; addition of up to 1.5 at.% Hf extends this range to 85.3 at.% Co. The lattice constants, Curie temperature and room-temperature saturation magnetization of the PrCo5+δ phase approximately follow the Vegard's law as if this phase were transitional between the stoichiometric PrCo5 phase and the hypothetical disordered Pr2Co17 phase. Hafnium decreases the saturation magnetization of the Pr1−xHfxCo5+δ phase, but has no significant effect on its Curie temperature. The highest saturation magnetization of 12.9 kG was observed in the off-stoichiometric binary alloy Pr84.5Co15.5. The solubility of Co in the PrCo5 structure was found to decrease with decreasing the homogenization temperature; only Pr1−xHfxCo5 alloys exhibited the single-phase structure after annealing at 900 °C." @default.
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- W2066920538 date "2011-02-01" @default.
- W2066920538 modified "2023-09-24" @default.
- W2066920538 title "Stability of PrCo5+δ and Pr1−xHfxCo5+δ alloys with TbCu7-type structure at 900–1150°C and their magnetic properties" @default.
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- W2066920538 doi "https://doi.org/10.1016/j.jallcom.2010.11.090" @default.
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