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• W2066936309 startingPage "5764" @default.
• W2066936309 abstract "Measurements of relaxation time in epoxy resin [poly(bisphenol $A$-co-epichlorohydrin), glycidyl end capped] in the supercooled liquid state have been carried out using dielectric spectroscopy over the frequency range from 10 mHz to 10 MHz as a function of pressure (up to $p=250mathrm{MPa}$) and as a function of temperature. To our knowledge, this is the first time a two-dimensional surface of relaxation times $ensuremath{tau}=ensuremath{tau}(T,p)$ in epoxy resin has been plotted. The pressure and the temperature dependence of structural relaxation times are in good agreement with the extended Vogel-Fulcher-Tammann equation. For isobaric data, the fragility of the epoxy system reveals a tendency to decrease at elevated pressures. By using pressure as an additional variable, the influence of pressure on glass transition temperature ${T}_{g}$ has been determined." @default.
• W2066936309 created "2016-06-24" @default.
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• W2066936309 date "1997-11-01" @default.
• W2066936309 modified "2023-09-27" @default.
• W2066936309 title "Dielectric relaxation of glass-forming epoxy resin under high pressure" @default.
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• W2066936309 doi "https://doi.org/10.1103/physreve.56.5764" @default.
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