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- W2066937965 abstract "The trans and cis diastereoisomers of 2-bromo-6-t-butylcyclohexanone (7 and 8) and of 2-bromo-3-t-butylcyclohexanone (10 and 9) have been prepared and subjected to hydrogen bromide catalyzed isomerization. Whereas bromoketones 7 and 8 underwent only epimerization, isomers 9 and 10 were completely converted into an equilibrium mixture of cis- and trans-2-bromo-5-t-butylcyclohexanone (12 and 13). The spectral parameters (IR, UV, NMR), as well as the equilibrium distribution of the couple 7-8, were consistent with chair conformations for compounds 7, 8 and 9, but indicated for isomer 10 a flexible form in which both the bromine-t-butyl steric interaction and the electrostatic repulsion between Br and CO group are relieved." @default.
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- W2066937965 date "1978-01-01" @default.
- W2066937965 modified "2023-10-18" @default.
- W2066937965 title "The influence of a t-Butyl group on the conformational equilibrium and the Hydrogen Bromide catalyzed isomerization of 2-Bromocyclohexanones" @default.
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- W2066937965 doi "https://doi.org/10.1016/s0040-4020(01)93597-5" @default.
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