FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066942907> ?p ?o ?g. }

• W2066942907 endingPage "178" @default.
• W2066942907 startingPage "173" @default.
• W2066942907 abstract "Reaction of Me3M (M  Al, Ga) with 1-aminoadamantane, Ada, in toluene affords crystalline complexes of the type [Me2M-Ada]2. The gallium compound, I, isomorphous with the aluminum compound, II, crystallizes in the triclinic space group P1 with unit cell parameters a=6.728(1), b=9.957(2), c=10.341(2) Å, α=74.30(1), β=73.94(1), γ=72.19(1)°, V=620.6(2) Å3 and Dcalc=1.34 g cm−3 for Z=1. Least-squares refinement based on 1794 observed reflections (I>3σ(I)) converged at R=0.059, Rw=0.080. I resides about a crystallographic center of symmetry and contains a planar Ga2N2 four-membered ring. The Ga2N2 ring has a mean GaN bond distance of 2.030(9) Å. The mean GaC bond distance in the dimethylgallium unit is 1.974(9) Å. The crystalline product [(i-Bu)Al-iminodibenzyl]2 (III), isolated from reaction of diisobutylaluminum hydride with iminodibenzyl, (C14H12)NH, in toluene, crystallizes in the triclinic space group P1 with unit cell parameters a=10.767(2), b=12.264(3), c=13.230(4) Å, α=75.57(2), β=74.14(2), γ=73.58(2)°, V=1583.7(7) Å3 and Dcalc=1.16 g cm−3 for Z=2. Least-squares refinement based on 2216 observed reflections (I>3σ(I)) converged at R=0.093, Rw=0.118. Compound III results from a unique condensation reaction in which ortho-metallation of one of the aromatic rings of iminodibenzyl was observed. Compound III has a mean AlN bond distance of 2.036(7) Å. The mean AlCisobutyl bond distance of 1.98(3) Å is comparable to 1.954(8) Å for the AlCaromatic fragment." @default.
• W2066942907 created "2016-06-24" @default.
• W2066942907 creator A5015744903 @default.
• W2066942907 creator A5021545559 @default.
• W2066942907 creator A5087950394 @default.
• W2066942907 date "1991-12-01" @default.
• W2066942907 modified "2023-10-18" @default.
• W2066942907 title "Group 13 chemistry of sterically hindered amines. Synthesis and molecular structure of [Me2M-Ada]2 (M  Al, Ga; Ada  1-aminoadamantane) and [(i-Bu)Al-iminodibenzyl]2" @default.
• W2066942907 cites W1823595950 @default.
• W2066942907 cites W1967169721 @default.
• W2066942907 cites W1967636414 @default.
• W2066942907 cites W1973133118 @default.
• W2066942907 cites W1982901546 @default.
• W2066942907 cites W1986609487 @default.
• W2066942907 cites W1986624405 @default.
• W2066942907 cites W1994803603 @default.
• W2066942907 cites W1999914144 @default.
• W2066942907 cites W2007677713 @default.
• W2066942907 cites W2030603525 @default.
• W2066942907 cites W2038752269 @default.
• W2066942907 cites W2042409878 @default.
• W2066942907 cites W2048116955 @default.
• W2066942907 cites W2050397207 @default.
• W2066942907 cites W2055335233 @default.
• W2066942907 cites W2059391081 @default.
• W2066942907 cites W2064856505 @default.
• W2066942907 cites W2067411296 @default.
• W2066942907 cites W2314527254 @default.
• W2066942907 cites W4255399835 @default.
• W2066942907 doi "https://doi.org/10.1016/s0020-1693(00)80250-9" @default.
• W2066942907 hasPublicationYear "1991" @default.
• W2066942907 type Work @default.
• W2066942907 sameAs 2066942907 @default.
• W2066942907 citedByCount "25" @default.
• W2066942907 countsByYear W20669429072013 @default.
• W2066942907 countsByYear W20669429072016 @default.
• W2066942907 crossrefType "journal-article" @default.
• W2066942907 hasAuthorship W2066942907A5015744903 @default.
• W2066942907 hasAuthorship W2066942907A5021545559 @default.
• W2066942907 hasAuthorship W2066942907A5087950394 @default.
• W2066942907 hasConcept C115624301 @default.
• W2066942907 hasConcept C155860418 @default.
• W2066942907 hasConcept C178790620 @default.
• W2066942907 hasConcept C185592680 @default.
• W2066942907 hasConcept C201194858 @default.
• W2066942907 hasConcept C2778142098 @default.
• W2066942907 hasConcept C2780378348 @default.
• W2066942907 hasConcept C2781311116 @default.
• W2066942907 hasConcept C42228675 @default.
• W2066942907 hasConcept C71240020 @default.
• W2066942907 hasConcept C8010536 @default.
• W2066942907 hasConceptScore W2066942907C115624301 @default.
• W2066942907 hasConceptScore W2066942907C155860418 @default.
• W2066942907 hasConceptScore W2066942907C178790620 @default.
• W2066942907 hasConceptScore W2066942907C185592680 @default.
• W2066942907 hasConceptScore W2066942907C201194858 @default.
• W2066942907 hasConceptScore W2066942907C2778142098 @default.
• W2066942907 hasConceptScore W2066942907C2780378348 @default.
• W2066942907 hasConceptScore W2066942907C2781311116 @default.
• W2066942907 hasConceptScore W2066942907C42228675 @default.
• W2066942907 hasConceptScore W2066942907C71240020 @default.
• W2066942907 hasConceptScore W2066942907C8010536 @default.
• W2066942907 hasIssue "2" @default.
• W2066942907 hasLocation W20669429071 @default.
• W2066942907 hasOpenAccess W2066942907 @default.
• W2066942907 hasPrimaryLocation W20669429071 @default.
• W2066942907 hasRelatedWork W1907485755 @default.
• W2066942907 hasRelatedWork W1969527728 @default.
• W2066942907 hasRelatedWork W1981289756 @default.
• W2066942907 hasRelatedWork W2012042927 @default.
• W2066942907 hasRelatedWork W2123678093 @default.
• W2066942907 hasRelatedWork W2137584480 @default.
• W2066942907 hasRelatedWork W2331334252 @default.
• W2066942907 hasRelatedWork W2370821912 @default.
• W2066942907 hasRelatedWork W2702775578 @default.
• W2066942907 hasRelatedWork W3145959138 @default.
• W2066942907 hasVolume "190" @default.
• W2066942907 isParatext "false" @default.
• W2066942907 isRetracted "false" @default.
• W2066942907 magId "2066942907" @default.
• W2066942907 workType "article" @default.