Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066947975> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2066947975 abstract "The alkyne hydrophosphonylation is an atom economical method for the synthesis of vinylphosphonates that are compounds of both biological and synthetic relevance. Recent approaches based on the use of metal catalysts have only partially solved the problems of the reaction selectivity as well as of economical and large amount production. We report in this Letter on a metal-free approach that leads to E-vinylphosphonates in high yields. The approach is based on a two-step one-pot synthesis, namely: (a) photoinduced anti-Markovnikov addition of a H-phosphonate to alkynes to give mixtures of E- and Z-vinylphosphonates, and (b) cysteine promoted photoinduced conversion of the crude mixtures of adducts into E-isomers (58–92% overall yields)." @default.
- W2066947975 created "2016-06-24" @default.
- W2066947975 creator A5025961287 @default.
- W2066947975 creator A5040406233 @default.
- W2066947975 creator A5088753995 @default.
- W2066947975 date "2015-01-01" @default.
- W2066947975 modified "2023-09-24" @default.
- W2066947975 title "Metal-free synthesis of E-vinylphosphonates via photoinduced alkyne hydrophosphonylation and thiol promoted isomerization sequence" @default.
- W2066947975 cites W1890693902 @default.
- W2066947975 cites W1948019169 @default.
- W2066947975 cites W1965810302 @default.
- W2066947975 cites W1973902504 @default.
- W2066947975 cites W1974452548 @default.
- W2066947975 cites W1983767005 @default.
- W2066947975 cites W1986513210 @default.
- W2066947975 cites W1992397435 @default.
- W2066947975 cites W2050213698 @default.
- W2066947975 cites W2068780224 @default.
- W2066947975 cites W2075021268 @default.
- W2066947975 cites W2093882245 @default.
- W2066947975 cites W2112924165 @default.
- W2066947975 cites W2153957615 @default.
- W2066947975 cites W2158730144 @default.
- W2066947975 cites W2166027129 @default.
- W2066947975 cites W2319105527 @default.
- W2066947975 cites W2328010077 @default.
- W2066947975 cites W2329241456 @default.
- W2066947975 cites W2949065034 @default.
- W2066947975 cites W2951503656 @default.
- W2066947975 cites W2952848529 @default.
- W2066947975 doi "https://doi.org/10.1016/j.tetlet.2014.11.099" @default.
- W2066947975 hasPublicationYear "2015" @default.
- W2066947975 type Work @default.
- W2066947975 sameAs 2066947975 @default.
- W2066947975 citedByCount "6" @default.
- W2066947975 countsByYear W20669479752015 @default.
- W2066947975 countsByYear W20669479752016 @default.
- W2066947975 countsByYear W20669479752018 @default.
- W2066947975 countsByYear W20669479752021 @default.
- W2066947975 crossrefType "journal-article" @default.
- W2066947975 hasAuthorship W2066947975A5025961287 @default.
- W2066947975 hasAuthorship W2066947975A5040406233 @default.
- W2066947975 hasAuthorship W2066947975A5088753995 @default.
- W2066947975 hasConcept C126661725 @default.
- W2066947975 hasConcept C161790260 @default.
- W2066947975 hasConcept C178790620 @default.
- W2066947975 hasConcept C185592680 @default.
- W2066947975 hasConcept C188027245 @default.
- W2066947975 hasConcept C2778112365 @default.
- W2066947975 hasConcept C2779012754 @default.
- W2066947975 hasConcept C2781324293 @default.
- W2066947975 hasConcept C55493867 @default.
- W2066947975 hasConcept C75473681 @default.
- W2066947975 hasConceptScore W2066947975C126661725 @default.
- W2066947975 hasConceptScore W2066947975C161790260 @default.
- W2066947975 hasConceptScore W2066947975C178790620 @default.
- W2066947975 hasConceptScore W2066947975C185592680 @default.
- W2066947975 hasConceptScore W2066947975C188027245 @default.
- W2066947975 hasConceptScore W2066947975C2778112365 @default.
- W2066947975 hasConceptScore W2066947975C2779012754 @default.
- W2066947975 hasConceptScore W2066947975C2781324293 @default.
- W2066947975 hasConceptScore W2066947975C55493867 @default.
- W2066947975 hasConceptScore W2066947975C75473681 @default.
- W2066947975 hasFunder F4320324162 @default.
- W2066947975 hasLocation W20669479751 @default.
- W2066947975 hasLocation W20669479752 @default.
- W2066947975 hasOpenAccess W2066947975 @default.
- W2066947975 hasPrimaryLocation W20669479751 @default.
- W2066947975 hasRelatedWork W2066947975 @default.
- W2066947975 hasRelatedWork W2066997627 @default.
- W2066947975 hasRelatedWork W2320277076 @default.
- W2066947975 hasRelatedWork W2363498292 @default.
- W2066947975 hasRelatedWork W2395773616 @default.
- W2066947975 hasRelatedWork W2605206679 @default.
- W2066947975 hasRelatedWork W2949226866 @default.
- W2066947975 hasRelatedWork W2952183763 @default.
- W2066947975 hasRelatedWork W3004986603 @default.
- W2066947975 hasRelatedWork W4238592385 @default.
- W2066947975 isParatext "false" @default.
- W2066947975 isRetracted "false" @default.
- W2066947975 magId "2066947975" @default.
- W2066947975 workType "article" @default.