FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066966584> ?p ?o ?g. }

• W2066966584 abstract "The intermolecular dynamics of dilute solutions of CS2 in 1-alkyl-3-methylimidazolium bis[(trifluoromethane)sulfonyl]amide ([CnC1im][NTf2] for n = 1–4) were studied at 295 K using femtosecond optical Kerr effect (OKE) spectroscopy. The OKE spectra of the CS2/ionic liquid (IL) mixtures were analyzed using an additivity model to obtain the CS2 contribution to the OKE spectrum from which information about the intermolecular modes of CS2 in these mixtures was gleaned. The intermolecular spectrum of CS2 in these mixtures is lower in frequency and narrower than that of neat CS2, as found previously for CS2 in [C5C1im][NTf2]. Moreover, a dependence of the spectra on alkyl chain length is observed that is attributed to the interplay between electrostatic and dispersion interactions. The surprising result in this study is the solubility of CS2 in [C1C1im][NTf2], which involves the interaction of a nonpolar nonaromatic molecular solute and only the charged groups of the IL. We propose that the solubility of CS2 in [C1C1im][NTf2] is determined by three favorable factors – (1) large polarizability of the solute molecule; (2) small size of the solute molecule; and (3) low cohesive energy in the high-charge density regions of the IL." @default.
• W2066966584 created "2016-06-24" @default.
• W2066966584 creator A5003787880 @default.
• W2066966584 creator A5042633107 @default.
• W2066966584 creator A5046898233 @default.
• W2066966584 creator A5082510883 @default.
• W2066966584 date "2014-04-28" @default.
• W2066966584 modified "2023-10-16" @default.
• W2066966584 title "Probing the interplay between electrostatic and dispersion interactions in the solvation of nonpolar nonaromatic solute molecules in ionic liquids: An OKE spectroscopic study of CS₂/[C_nC₁im][NTf₂] mixtures (n = 1–4)" @default.
• W2066966584 cites W1764469087 @default.
• W2066966584 cites W1965152776 @default.
• W2066966584 cites W1969313848 @default.
• W2066966584 cites W1972052884 @default.
• W2066966584 cites W1973969142 @default.
• W2066966584 cites W1981481498 @default.
• W2066966584 cites W1986541549 @default.
• W2066966584 cites W1991010825 @default.
• W2066966584 cites W1991652602 @default.
• W2066966584 cites W1995744636 @default.
• W2066966584 cites W1995863104 @default.
• W2066966584 cites W1999714153 @default.
• W2066966584 cites W2000044586 @default.
• W2066966584 cites W2003401677 @default.
• W2066966584 cites W2004268875 @default.
• W2066966584 cites W2009897620 @default.
• W2066966584 cites W2011149424 @default.
• W2066966584 cites W2013478319 @default.
• W2066966584 cites W2017418558 @default.
• W2066966584 cites W2017898890 @default.
• W2066966584 cites W2020216004 @default.
• W2066966584 cites W2027385130 @default.
• W2066966584 cites W2033740917 @default.
• W2066966584 cites W2034536462 @default.
• W2066966584 cites W2044567650 @default.
• W2066966584 cites W2053010217 @default.
• W2066966584 cites W2057831874 @default.
• W2066966584 cites W2059289107 @default.
• W2066966584 cites W2062528445 @default.
• W2066966584 cites W2063217685 @default.
• W2066966584 cites W2063618473 @default.
• W2066966584 cites W2067685498 @default.
• W2066966584 cites W2072706452 @default.
• W2066966584 cites W2075495144 @default.
• W2066966584 cites W2077400462 @default.
• W2066966584 cites W2082292248 @default.
• W2066966584 cites W2083264982 @default.
• W2066966584 cites W2084543516 @default.
• W2066966584 cites W2085126706 @default.
• W2066966584 cites W2085989165 @default.
• W2066966584 cites W2089625391 @default.
• W2066966584 cites W2090404542 @default.
• W2066966584 cites W2091476857 @default.
• W2066966584 cites W2104251825 @default.
• W2066966584 cites W2109950211 @default.
• W2066966584 cites W2128228409 @default.
• W2066966584 cites W2150995105 @default.
• W2066966584 cites W2164386554 @default.
• W2066966584 cites W2318481604 @default.
• W2066966584 cites W2320271627 @default.
• W2066966584 cites W2331083790 @default.
• W2066966584 cites W3022806437 @default.
• W2066966584 cites W4214510387 @default.
• W2066966584 cites W4247178772 @default.
• W2066966584 cites W563664482 @default.
• W2066966584 doi "https://doi.org/10.1063/1.4872038" @default.
• W2066966584 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24784292" @default.
• W2066966584 hasPublicationYear "2014" @default.
• W2066966584 type Work @default.
• W2066966584 sameAs 2066966584 @default.
• W2066966584 citedByCount "21" @default.
• W2066966584 countsByYear W20669665842014 @default.
• W2066966584 countsByYear W20669665842015 @default.
• W2066966584 countsByYear W20669665842016 @default.
• W2066966584 countsByYear W20669665842017 @default.
• W2066966584 countsByYear W20669665842018 @default.
• W2066966584 countsByYear W20669665842019 @default.
• W2066966584 countsByYear W20669665842020 @default.
• W2066966584 countsByYear W20669665842021 @default.
• W2066966584 crossrefType "journal-article" @default.
• W2066966584 hasAuthorship W2066966584A5003787880 @default.
• W2066966584 hasAuthorship W2066966584A5042633107 @default.
• W2066966584 hasAuthorship W2066966584A5046898233 @default.
• W2066966584 hasAuthorship W2066966584A5082510883 @default.
• W2066966584 hasConcept C120665830 @default.
• W2066966584 hasConcept C121332964 @default.
• W2066966584 hasConcept C139287275 @default.
• W2066966584 hasConcept C147597530 @default.
• W2066966584 hasConcept C147789679 @default.
• W2066966584 hasConcept C148093993 @default.
• W2066966584 hasConcept C154881586 @default.
• W2066966584 hasConcept C155574463 @default.
• W2066966584 hasConcept C158622935 @default.
• W2066966584 hasConcept C159467904 @default.
• W2066966584 hasConcept C161790260 @default.
• W2066966584 hasConcept C166950319 @default.
• W2066966584 hasConcept C176672485 @default.
• W2066966584 hasConcept C177562468 @default.
• W2066966584 hasConcept C178790620 @default.
• W2066966584 hasConcept C185592680 @default.
• W2066966584 hasConcept C2780263894 @default.

• next