FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2066978211> ?p ?o ?g. }

• W2066978211 endingPage "1883" @default.
• W2066978211 startingPage "1875" @default.
• W2066978211 abstract "The activation–deactivation equilibrium of nitroxide-controlled radical polymerization of styrene at 123 °C was investigated. For this purpose the reaction solution was examined time dependently during the initial phase of the polymerization by using an SEC column combination providing a very good separation of the low-molecular weight species. By time-dependent measurement of the alkoxyamine concentration the activation rate of the alkoxyamines PhEt-TIPNO (N-tert-butyl-N-(2-methyl-1-phenyl-propyl)-O-(1-phenyl-ethyl)-hydroxylamine) kact = 3.2 × 10−3 s−1 and PhEt-BIPNO (N-tert-butyl-N-(1-isopropyl-2-methyl-propyl)-O-(1-phenyl-ethyl)-hydroxylamine) kact = 6.4 × 10−3 s−1 can be determined directly. Considering the Persistent Radical Effect theory, the measurement of the free nitroxide concentration allows to determine the pseudo-equilibrium constant of dissociation/combination between dormant and active species for polystyryl-TIPNO and polystyryl-BIPNO, K = 7.5 × 10−9 mol/L and 1.08 × 10−8 mol/L, respectively." @default.
• W2066978211 created "2016-06-24" @default.
• W2066978211 creator A5007584579 @default.
• W2066978211 creator A5037771718 @default.
• W2066978211 creator A5051345035 @default.
• W2066978211 date "2007-03-01" @default.
• W2066978211 modified "2023-09-25" @default.
• W2066978211 title "Kinetics of nitroxide-controlled radical polymerization during the non-stationary state" @default.
• W2066978211 cites W1964575611 @default.
• W2066978211 cites W1968922359 @default.
• W2066978211 cites W1970388577 @default.
• W2066978211 cites W1971674116 @default.
• W2066978211 cites W1977660863 @default.
• W2066978211 cites W1985252575 @default.
• W2066978211 cites W1993758718 @default.
• W2066978211 cites W2004117309 @default.
• W2066978211 cites W2007073153 @default.
• W2066978211 cites W2009177957 @default.
• W2066978211 cites W2012646500 @default.
• W2066978211 cites W2015007875 @default.
• W2066978211 cites W2021235101 @default.
• W2066978211 cites W2031435246 @default.
• W2066978211 cites W2036295636 @default.
• W2066978211 cites W2036707632 @default.
• W2066978211 cites W2050381703 @default.
• W2066978211 cites W2054178986 @default.
• W2066978211 cites W2055393399 @default.
• W2066978211 cites W2060571716 @default.
• W2066978211 cites W2069841520 @default.
• W2066978211 cites W2077235613 @default.
• W2066978211 cites W2085531273 @default.
• W2066978211 cites W2104018884 @default.
• W2066978211 cites W2136380772 @default.
• W2066978211 cites W2144122182 @default.
• W2066978211 cites W2153925194 @default.
• W2066978211 doi "https://doi.org/10.1016/j.polymer.2007.02.016" @default.
• W2066978211 hasPublicationYear "2007" @default.
• W2066978211 type Work @default.
• W2066978211 sameAs 2066978211 @default.
• W2066978211 citedByCount "11" @default.
• W2066978211 countsByYear W20669782112012 @default.
• W2066978211 countsByYear W20669782112013 @default.
• W2066978211 countsByYear W20669782112014 @default.
• W2066978211 countsByYear W20669782112020 @default.
• W2066978211 crossrefType "journal-article" @default.
• W2066978211 hasAuthorship W2066978211A5007584579 @default.
• W2066978211 hasAuthorship W2066978211A5037771718 @default.
• W2066978211 hasAuthorship W2066978211A5051345035 @default.
• W2066978211 hasConcept C102931765 @default.
• W2066978211 hasConcept C104264131 @default.
• W2066978211 hasConcept C111998727 @default.
• W2066978211 hasConcept C121332964 @default.
• W2066978211 hasConcept C147789679 @default.
• W2066978211 hasConcept C148898269 @default.
• W2066978211 hasConcept C155647269 @default.
• W2066978211 hasConcept C15920480 @default.
• W2066978211 hasConcept C161790260 @default.
• W2066978211 hasConcept C169912494 @default.
• W2066978211 hasConcept C178790620 @default.
• W2066978211 hasConcept C185592680 @default.
• W2066978211 hasConcept C188027245 @default.
• W2066978211 hasConcept C2775999725 @default.
• W2066978211 hasConcept C2776142628 @default.
• W2066978211 hasConcept C2777566558 @default.
• W2066978211 hasConcept C37263863 @default.
• W2066978211 hasConcept C44228677 @default.
• W2066978211 hasConcept C521977710 @default.
• W2066978211 hasConcept C53856295 @default.
• W2066978211 hasConcept C62520636 @default.
• W2066978211 hasConcept C75473681 @default.
• W2066978211 hasConceptScore W2066978211C102931765 @default.
• W2066978211 hasConceptScore W2066978211C104264131 @default.
• W2066978211 hasConceptScore W2066978211C111998727 @default.
• W2066978211 hasConceptScore W2066978211C121332964 @default.
• W2066978211 hasConceptScore W2066978211C147789679 @default.
• W2066978211 hasConceptScore W2066978211C148898269 @default.
• W2066978211 hasConceptScore W2066978211C155647269 @default.
• W2066978211 hasConceptScore W2066978211C15920480 @default.
• W2066978211 hasConceptScore W2066978211C161790260 @default.
• W2066978211 hasConceptScore W2066978211C169912494 @default.
• W2066978211 hasConceptScore W2066978211C178790620 @default.
• W2066978211 hasConceptScore W2066978211C185592680 @default.
• W2066978211 hasConceptScore W2066978211C188027245 @default.
• W2066978211 hasConceptScore W2066978211C2775999725 @default.
• W2066978211 hasConceptScore W2066978211C2776142628 @default.
• W2066978211 hasConceptScore W2066978211C2777566558 @default.
• W2066978211 hasConceptScore W2066978211C37263863 @default.
• W2066978211 hasConceptScore W2066978211C44228677 @default.
• W2066978211 hasConceptScore W2066978211C521977710 @default.
• W2066978211 hasConceptScore W2066978211C53856295 @default.
• W2066978211 hasConceptScore W2066978211C62520636 @default.
• W2066978211 hasConceptScore W2066978211C75473681 @default.
• W2066978211 hasIssue "7" @default.
• W2066978211 hasLocation W20669782111 @default.
• W2066978211 hasOpenAccess W2066978211 @default.
• W2066978211 hasPrimaryLocation W20669782111 @default.
• W2066978211 hasRelatedWork W2019953135 @default.
• W2066978211 hasRelatedWork W2039212248 @default.

• next