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- W2067010736 abstract "Capillary electrophoresis (CE) was used for the determination of ionisation constants (pKa) of a variety of organic bases in aqueous acetonitrile solutions over the range 0-60% (v/v) acetonitrile. These bases are used as test compounds in HPLC column evaluation, thus knowledge of their pKa in hydro-organic solutions is useful. The base pKa decreased with acetonitrile concentration and significant shifts from the aqueous pKa (up to -0.8) were found using 60% acetonitrile. The CE application was confirmed to be very suitable for fast and accurate pKa measurement in aqueous organic solutions." @default.
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- W2067010736 date "2003-07-01" @default.
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- W2067010736 title "Determination of pKa values of organic bases in aqueous acetonitrile solutions using capillary electrophoresis" @default.
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- W2067010736 doi "https://doi.org/10.1016/s0021-9673(03)00717-9" @default.
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