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- W2067024300 abstract "As part of an ongoing project concerning the synthesis of enantiomerically pure α-hydroxy β-amino acids, we have now developed a general strategy allowing the synthesis of anti-α-alkyl α-hydroxy β-amino acids. Our procedure involves the intermediate formation of trans-oxazolines, which are alkylated at C-5 with good to high diastereoselectivity and then hydrolysed under mildly acidic conditions, affording in quantitative yield the corresponding hydroxy amides. The starting (R)-3-amino-3-phenylpropanoic acid and (S)-3-aminobutanoic acid were obtained in enantiomerically pure form by selective enzymatic hydrolysis of the corresponding phenylacetylamides with penicillin G acylase." @default.
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- W2067024300 date "1999-01-01" @default.
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- W2067024300 title "A New Diastereoselective Synthesis ofanti-α-Alkyl α-Hydroxy β-Amino Acids" @default.
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- W2067024300 doi "https://doi.org/10.1002/(sici)1099-0690(199901)1999:1<155::aid-ejoc155>3.0.co;2-a" @default.
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