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- W2067046965 abstract "A catalyst based on immobilization of tungstate ions (WO42−) inside the mesochannels of periodic mesoporous organosilica comprising bridged ionic liquid (1,3-bis(3-trimethoxysilylpropyl)imidazolium chloride) has been synthesized and characterized. This catalyst was then employed for the selective oxidation of organic sulfides to the corresponding sulfoxides or sulfones. The final synthesized catalyst was characterized by various techniques such as nitrogen sorption analysis, transmission electron microscopy, and thermogravimetric analysis. The catalyst was also applied to the selective oxidation of sulfides containing readily oxidizable functional groups such as hydroxyl, allylic, and even challenging aliphatic sulfides. Interestingly, it was found that on changing the reaction medium from aqueous methanol to aqueous acetonitrile, the product selectivity was changed successfully from sulfoxide to sulfone with good to excellent yields. Moreover, the catalyst can also be recovered and reused efficiently in nine subsequent reaction cycles without any remarkable decrease in the catalyst activity and selectivity." @default.
- W2067046965 created "2016-06-24" @default.
- W2067046965 creator A5007285706 @default.
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- W2067046965 creator A5040045684 @default.
- W2067046965 creator A5063939311 @default.
- W2067046965 creator A5079773707 @default.
- W2067046965 date "2015-03-11" @default.
- W2067046965 modified "2023-10-16" @default.
- W2067046965 title "Tungstate Supported on Periodic Mesoporous Organosilica with Imidazolium Framework as an Efficient and Recyclable Catalyst for the Selective Oxidation of Sulfides" @default.
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