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- W2067054047 abstract "Abstract CN radicals have been generated in their X 2 Σ + ( v =0) and ( v = 1 ) levels by pulsed laser photolysis of NCNO at 532 nm, and time-resolved laser-induced fluorescence has been used to measure the rates of their removal by H 2 , HC1 and HBr. The rate constants for removal of CN( v = 1 ) by these three species are 1.2 ± 0.3, 1.1 ± 0.2 and 1.3 ± 0.1 times the rate constants for reaction of CN( v =0). The results can be interpreted in terms of vibrationally adiabatic theory and a CN vibrational frequency which is almost the same in the transition state as in the isolated radical." @default.
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- W2067054047 date "1986-12-01" @default.
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- W2067054047 title "Kinetics of CN(v=0) and CN(v=1) with H2 HCl and HBr" @default.
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- W2067054047 doi "https://doi.org/10.1016/0009-2614(86)80089-6" @default.
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