Matches in SemOpenAlex for { <https://semopenalex.org/work/W2067055032> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2067055032 endingPage "4886" @default.
- W2067055032 startingPage "4877" @default.
- W2067055032 abstract "Collision-induced vibrational energy transfer has been studied from two vibrational levels at intermediate state density in S1 p-difluorobenzene in a supersonic free jet expansion at ∼30–40 K. Transfer was studied from the 7181 (Evib=751 cm−1) and 84 (Evib=733 cm−1) states where ρvib is ∼0.4 states per cm−1. Data were obtained for He, Ne, H2, and D2 for both levels and also for Ar and Kr for 7181. There is some doubt concerning the influence of predissociation of van der Waals complexes on the spectra for these latter partners. The data analysis for 7181 is quantitative for all collision partners. For 84 the analysis is quantitative for H2 and D2 but qualitative for He and Ne because of poor signal levels. The state-to-state propensity rules in this region of the vibrational manifold are compared with those observed at lower state densities, particularly those from 82. The main feature to emerge is a lack of predictability of the major relaxation pathways. There is a clear increase in the importance of transfers involving multiple changes in vibrational quanta for all situations studied and at times such transfers totally dominate. This occurs in spite of the possibility for loss of one quantum of ν8, which is a very efficient channel in transfer from 82. Collision partners that show similar state-to-state branching ratios for 82 show quite different branching ratios for 7181 and for 84." @default.
- W2067055032 created "2016-06-24" @default.
- W2067055032 creator A5032863874 @default.
- W2067055032 creator A5050972823 @default.
- W2067055032 date "1998-03-22" @default.
- W2067055032 modified "2023-09-26" @default.
- W2067055032 title "State-to-state vibrational energy transfer in S1 p-difluorobenzene at intermediate state densities: A change in propensity rules" @default.
- W2067055032 cites W1972995913 @default.
- W2067055032 cites W1983131870 @default.
- W2067055032 cites W1984289014 @default.
- W2067055032 cites W1986059028 @default.
- W2067055032 cites W1993237409 @default.
- W2067055032 cites W1994740326 @default.
- W2067055032 cites W1996960719 @default.
- W2067055032 cites W2005628757 @default.
- W2067055032 cites W2005900157 @default.
- W2067055032 cites W2013380903 @default.
- W2067055032 cites W2017064379 @default.
- W2067055032 cites W2017607907 @default.
- W2067055032 cites W2018474009 @default.
- W2067055032 cites W2019217639 @default.
- W2067055032 cites W2024062034 @default.
- W2067055032 cites W2030111068 @default.
- W2067055032 cites W2033082383 @default.
- W2067055032 cites W2033328038 @default.
- W2067055032 cites W2037022641 @default.
- W2067055032 cites W2037382802 @default.
- W2067055032 cites W2037712343 @default.
- W2067055032 cites W2042976043 @default.
- W2067055032 cites W2042994552 @default.
- W2067055032 cites W2044939118 @default.
- W2067055032 cites W2051559569 @default.
- W2067055032 cites W2057514196 @default.
- W2067055032 cites W2068642215 @default.
- W2067055032 cites W2073719842 @default.
- W2067055032 cites W2095316750 @default.
- W2067055032 cites W2096698601 @default.
- W2067055032 cites W2120726189 @default.
- W2067055032 cites W2953133595 @default.
- W2067055032 doi "https://doi.org/10.1063/1.475923" @default.
- W2067055032 hasPublicationYear "1998" @default.
- W2067055032 type Work @default.
- W2067055032 sameAs 2067055032 @default.
- W2067055032 citedByCount "3" @default.
- W2067055032 crossrefType "journal-article" @default.
- W2067055032 hasAuthorship W2067055032A5032863874 @default.
- W2067055032 hasAuthorship W2067055032A5050972823 @default.
- W2067055032 hasConcept C11413529 @default.
- W2067055032 hasConcept C121332964 @default.
- W2067055032 hasConcept C121704057 @default.
- W2067055032 hasConcept C126061179 @default.
- W2067055032 hasConcept C178790620 @default.
- W2067055032 hasConcept C181500209 @default.
- W2067055032 hasConcept C184779094 @default.
- W2067055032 hasConcept C185592680 @default.
- W2067055032 hasConcept C206175624 @default.
- W2067055032 hasConcept C2781077158 @default.
- W2067055032 hasConcept C32909587 @default.
- W2067055032 hasConcept C38652104 @default.
- W2067055032 hasConcept C41008148 @default.
- W2067055032 hasConcept C46460574 @default.
- W2067055032 hasConcept C48103436 @default.
- W2067055032 hasConcept C84662259 @default.
- W2067055032 hasConceptScore W2067055032C11413529 @default.
- W2067055032 hasConceptScore W2067055032C121332964 @default.
- W2067055032 hasConceptScore W2067055032C121704057 @default.
- W2067055032 hasConceptScore W2067055032C126061179 @default.
- W2067055032 hasConceptScore W2067055032C178790620 @default.
- W2067055032 hasConceptScore W2067055032C181500209 @default.
- W2067055032 hasConceptScore W2067055032C184779094 @default.
- W2067055032 hasConceptScore W2067055032C185592680 @default.
- W2067055032 hasConceptScore W2067055032C206175624 @default.
- W2067055032 hasConceptScore W2067055032C2781077158 @default.
- W2067055032 hasConceptScore W2067055032C32909587 @default.
- W2067055032 hasConceptScore W2067055032C38652104 @default.
- W2067055032 hasConceptScore W2067055032C41008148 @default.
- W2067055032 hasConceptScore W2067055032C46460574 @default.
- W2067055032 hasConceptScore W2067055032C48103436 @default.
- W2067055032 hasConceptScore W2067055032C84662259 @default.
- W2067055032 hasIssue "12" @default.
- W2067055032 hasLocation W20670550321 @default.
- W2067055032 hasOpenAccess W2067055032 @default.
- W2067055032 hasPrimaryLocation W20670550321 @default.
- W2067055032 hasRelatedWork W1969031620 @default.
- W2067055032 hasRelatedWork W1974312846 @default.
- W2067055032 hasRelatedWork W1985137830 @default.
- W2067055032 hasRelatedWork W1995551930 @default.
- W2067055032 hasRelatedWork W2010113741 @default.
- W2067055032 hasRelatedWork W2037633667 @default.
- W2067055032 hasRelatedWork W2039955073 @default.
- W2067055032 hasRelatedWork W2094462541 @default.
- W2067055032 hasRelatedWork W4283362803 @default.
- W2067055032 hasRelatedWork W2082313586 @default.
- W2067055032 hasVolume "108" @default.
- W2067055032 isParatext "false" @default.
- W2067055032 isRetracted "false" @default.
- W2067055032 magId "2067055032" @default.
- W2067055032 workType "article" @default.