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- W2067065027 abstract "Second order non linear optical <b>(NLO)</b> properties of <b>sPMMA</b> based host-guest systems containing eight dimethylaminobenzylidene -1, 3 - indandione <b>(DMABI)</b> related chromophores have been investigated by means of quantum chemical calculations and <b>SHG </b>experimental characterization. <i><b>Ab initio</b></i> calculations with basis set <b>6-31G </b>were used for molecular geometry determination as well as in the calculations of molecular hyperpolarizability by <b>FF</b> approach. Influence of the chromophore concentration on the host-guest film NLO performance was obtained by SHG Maker fringe experiments. The highest value of <i>d<sup>532</sup><sub>33</sub></i> =80 pm/V (frequency corrected value <i>d<sup>0</sup><sub>33</sub></i> =12 pm/V) at chromophore concentration 15 %wt have been recorded for tret-butyl substituted <b>DMABI </b>chromophore." @default.
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- W2067065027 date "2006-04-21" @default.
- W2067065027 modified "2023-10-02" @default.
- W2067065027 title "Novel second-order nonlinear optical polymer materials containing indandione derivativatives as a chromophore" @default.
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- W2067065027 doi "https://doi.org/10.1117/12.661937" @default.
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