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- W2067076228 abstract "Reaction of laser-ablated CuCl molecules with dioxygen upon condensation in excess argon results in IR absorption at 1175.0 cm−1, which is assigned to the O–O stretching vibration of the ClCu(O2) molecule based on isotopic substituted experiments. DFT calculations predicted a 3B1 ground state ClCu(O2), in which the O2 unit possesses a η2 binding mode to the metal center with C2v symmetry. Similar results were obtained in laser-ablated NiCl and O2 reactions. The O–O stretching vibration of the 4A1 ground state ClNi(O2) molecule was observed at 1097.7 cm−1 in solid argon." @default.
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- W2067076228 date "2000-07-01" @default.
- W2067076228 modified "2023-09-25" @default.
- W2067076228 title "Dioxygen bound to copper and nickel halides: matrix-isolation FTIR and DFT studies on ClCu(O2) and ClNi(O2) molecules" @default.
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- W2067076228 doi "https://doi.org/10.1016/s0009-2614(00)00639-4" @default.
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