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• W2067103484 abstract "A series of new chiral oxazoline-1,3-dithianes has been easily synthesized and used as ligands for asymmetric catalysis. The conjugate addition of Et2Zn to enones resulted in ees of up to 69%, whereas the Pd-catalyzed allylic alkylation led to the expected products in almost quantitative yields and up to 90% enantioselectivity. The ligand’s conformation has been explored using a combination of X-ray and NMR measurements, indicating the presence of a remarkable anomeric effect, which accounts for the preference of the oxazoline ring for the axial location." @default.
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• W2067103484 date "2005-10-01" @default.
• W2067103484 modified "2023-09-27" @default.
• W2067103484 title "Chiral oxazoline-1,3-dithianes: new effective nitrogen–sulfur donating ligands in asymmetric catalysis" @default.
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• W2067103484 doi "https://doi.org/10.1016/j.tetasy.2005.08.043" @default.
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